The sources and interpretation of Olympic Law

In this article, Mark James and Guy Osborn discuss how the relationships between the various members of the Olympic Movement are governed by the Olympic Charter and the legal framework within which an edition of the Olympic Games is organised. The legal status of the Charter and its interpretation by the Court of Arbitration for Sport are examined to identify who is subject to its terms and how challenges to its requirements can be made. Finally, by using the UK legislation that has been enacted to regulate advertising and trading at London 2012, the far-reaching and sometimes unexpected reach of Olympic Law is explored

PRE-FETCHING BATCHED ADVERTISEMENTS ON MOBILE DEVICES

A mobile device may include an advertisement subsystem that can transmit ad requests to an advertisement network to receive batched advertisements to be stored in an ad cache. When an application executing on the mobile device requests an advertisement from the advertisement subsystem, the advertisement subsystem can select and serve the prefetched advertisement even if the mobile device is offline. Impression and/or performance data may be transmitted to the advertisement network once the mobile device is online. In some implementations, the advertisement subsystem can combine signal data from multiple applications having differing permissions to create a more comprehensive ad request. In some instances, the advertisement subsystem may request batched advertisements only when network connectivity is strong and/or when connected via a wifi connection. In some instances, the advertisement subsystem may select and serve advertisements from an ad cache based on current signals for the device and/or an application executing on the device, such as a location, movement, recent applications, etc

Temperature Dependence Of The Electronic Absorption Spectrum Of NO2

The nitrogen dioxide (NO2) radical is composed of the two most abundant elements in the atmosphere, where it can be formed in a variety of ways including combustion, detonation of energetic materials, and lightning. Relevant also to smog and ozone cycles, together these processes span a wide range of temperatures. Remarkably, high-resolution NO2 electronic absorption spectra have only been reported in a narrow range below about 300 K. Previously, we reported [ J. Phys. Chem. A 2021, 125, 5519−5533 ] the construction of quasi-diabatic potential energy surfaces (PESs) for the lowest four electronic states (X̃, Ã, B̃, and C̃) of NO2. In addition to three-dimensional PESs based on explicitly correlated MRCI(Q)-F12/VTZ-F12 ab initio data, the geometry dependence of each component of the dipoles and transition dipoles was also mapped into fitted surfaces. The multiconfigurational time-dependent Hartree (MCTDH) method was then used to compute the 0 K electronic absorption spectrum (from the ground rovibrational initial state) employing those energy and transition dipole surfaces. Here, in an extension of that work, we report an investigation into the effects of elevated temperature on the spectrum, considering the effects of the population of rotationally and vibrationally excited initial states. The calculations are complemented by new experimental measurements. Spectral contributions from hundreds of rotational states up to N = 20 and from 200 individually-characterized vibrational states were computed. A spectral simulation tool was developed that enables modeling the spectrum at various temperatures─by weighting individual spectral contributions via the partition function, or for pure excited initial states, which can be probed via transient absorption spectroscopy. We validate these results against experimental absorption spectroscopy data at high temperatures, as well as via a new measurement from the (1,0,1) initial vibrational state

Warrior vehicle fleet sustainment using intelligent agent simulation

2nd International Through-Life Engineering Services Conference (TESConf 2013), 5-6 November 2013, Cranfield University, Bedfordshire, UKThe Warrior Infantry Fighting Vehicle(IFV) is one of the key tracked combat vehicles in the UK Army. It was first introduced in 1988. A modernisation programme is currently underway to enhance 643 vehicles to serve to 2040 and beyond. The Warrior is typical of military assets that have to be acquired, maintained, supported and deployed. Effective materials and logistics support for the life of the asset is necessary to give the army a capability to defend the country and keep world peace. In the military world, events are uncertain. An asset can be used relatively lightly in peace time for training and readiness preparation. When it is deployed, it is used intensely and probably in situations not foreseen in the original design specification. Compared with a commercial vehicle that is designed to be continuously heavily used, military uncertainties make the planning for spares and repairs very difficult. Responding to the dynamics of military logistics, inventory planners have to make decisions on how many spares to order from the manufacturer and when, where to store the spares, and when to send them to the units. Maintenance decisions are also made by military engineers to pull vehicles into depots for scheduled maintenance, deal with unexpected repairs, and make sure all people, equipment and spares are coordinated for the maintenance work. Planning for the worst case scenarios provides enhanced resilience to military needs, but is likely to be unnecessarily costly. Compared with an inventory management problem that has steady demand and supply, optimal military logistics could be better served by adapting the behaviour of the planners to suit the dynamics of the deployment scenarios. This paper reports on a military logistics sustainment model built using an agent based simulation platform, with the Warrior vehicle fleet as the case study. The model proves an effective tool to help military planners evaluate different spares inventory policies to match deployment demands

Expression of a CO2-permeable aquaporin enhances mesophyll conductance in the C4 species setaria viridis

A fundamental limitation of photosynthetic carbon fixation is the availability of CO2. In C4 plants, primary carboxylation occurs in mesophyll cytosol, and little is known about the role of CO2 diffusion in facilitating C4 photosynthesis. We have examined the expression, localization, and functional role of selected plasma membrane intrinsic aquaporins (PIPs) from Setaria italica (foxtail millet) and discovered that SiPIP2;7 is CO2-permeable. When ectopically expressed in mesophyll cells of S. viridis (green foxtail), SiPIP2;7 was localized to the plasma membrane and caused no marked changes in leaf biochemistry. Gas-exchange and C18O16O discrimination measurements revealed that targeted expression of SiPIP2;7 enhanced the conductance to CO2 diffusion from the intercellular airspace to the mesophyll cytosol. Our results demonstrate that mesophyll conductance limits C4 photosynthesis at low pCO2 and that SiPIP2;7 is a functional CO2 permeable aquaporin that can improve CO2 diffusion at the airspace/mesophyll interface and enhance C4 photosynthesis